The Milsmann Group

At West Virginia University

41.

Photochemical C–C Bond Formation in Luminescent Zirconium Complexes with CNN Pincer Ligands.

Yu Zhang, Jeffrey L. Petersen, and Carsten Milsmann*, Organometallics 2018, available online, DOI: 10.1021/acs.organomet.8b00388

 

40.

A Zirconium Photosensitizer with a Long-Lived Excited State: Mechanistic Insight into Photoinduced Single-Electron Transfer.

Yu Zhang, Tia S. Lee, Jeffrey L. Petersen, and Carsten Milsmann*, J. Am. Chem. Soc. 2018, 140, 5934.

 

39.

Synthesis of a Cyclophane Bearing Two Benz[a]anthracene Units Connected at the 5 and 7 Positions with Two Naphth-1,4-diyl Groups.

Haresh Thakellapalli, Behzad Farajidizaji, Shuangjiang Li, Josef C. Heller, Yu Zhang, Novruz G. Akhmedov, Carsten Milsmann, Jeffrey L. Petersen, Kung K. Wang, J. Org. Chem. 2018, 83, 2455.

 

38.

Redox Chemistry of Bis(pyrrolyl)pyridine Chromium and Molybdenum Complexes: An Experimental and Density Functional Theoretical Study.

Anitha S. Gowda, Jeffrey L. Petersen, Carsten Milsmann*, Inorg. Chem. 2018, 57, 1919.

 

37.

Synthesis and Structure of a Functionalized [9]Cycloparaphenylene Bearing Three Indeno[2,1-a]fluorene-11,12-dione-2,9-diyl Units.

Shuangjiang Li, Merfat Aljhdli, Haresh Thakellapalli, Behzad Farajidizaji, Yu Zhang, Novruz G. Akhmedov, Carsten Milsmann, Brian V. Popp, Kung K. Wang, Org. Lett. 2017, 19, 4078.

 

36.

A Luminescent Zirconium(IV) Complex as a Molecular Photosensitizer for Visible Light Photoredox Catalysis.

Yu Zhang, Jeffrey L. Petersen, Carsten Milsmann*, J. Am. Chem. Soc. 2016, 138, 13115.

 

Prior to WVU

35.

N−N Bond Cleavage of 1,2-Diarylhydrazines and N−H Bond Formation via H-Atom Transfer in Vanadium Complexes Supported by a Redox-Active Ligand.

Carsten Milsmann, Scott P. Semproni, Paul J. Chirik, J. Am. Chem. Soc. 2014, 136, 12099.

 

34.

Four-Coordinate Cobalt Pincer Complexes: Electronic Structure Studies and Ligand Modification by Homolytic and Heterolytic Pathways.

Scott P. Semproni, Carsten Milsmann, Paul J. Chirik, J. Am. Chem. Soc. 2014, 136, 9211.

 

33.

Synthesis, Electronic Structure and Reactivity of Bis(imino)pyridine Iron Carbene Complexes: Evidence for a Carbene Radical.

Sarah K. Russell, Jordan M. Hoyt, Suzanne C. Bart, Carsten Milsmann, S. Chantal E. Stieber, Scott P. Semproni, Serena DeBeer, Paul J. Chirik, Chem. Sci. 2014, 5, 1168.

 

32.

Catalytic Hydrogenation Activity and Electronic Structure Determination of Bis(arylimidazol-2-ylidene)pyridine Cobalt Alkyl and Hydride Complexes.

Renyuan Yu, Jonathan M. Darmon, Carsten Milsmann, Grant Margulieux, S. Chantal E. Stieber, Serena DeBeer, Paul J. Chirik, J. Am. Chem. Soc. 2013, 135, 13168.

 

31.

Reversible Carbon-Carbon Bond Formation Induced by Oxidation and Reduction at a Redox-Active Cobalt Complex.

Crisita C. H. Atienza, Carsten Milsmann, Scott P. Semproni, Zoe R. Turner, Paul J. Chirik, Inorg. Chem. 2013, 52, 5403.

 

30.

Redox-Induced N2 Hapticity Switching in Zirconocene Dinitrogen Complexes.

Scott P. Semproni, Donald J. Knobloch, Carsten Milsmann, Paul J. Chirik, Angew. Chem. Int. Ed. 2013, 52, 5372.

 

29.

Oxidation and Reduction of Bis(imino)pyridine Iron Dinitrogen Complexes: Evidence for Formation of a Chelate Trianion.

Aaron M. Tondreau, S. Chantal E. Stieber, Carsten Milsmann, Emil Lobkovsky, Thomas Weyhermüller, Paul J. Chirik, Inorg. Chem. 2013, 52, 635.

 

28.

Spin Crossover in a 3,5-Bis(2-pyridyl)-1,2,4-triazolate-Bridged Dinuclear Iron(II) Complex [{Fe(NCBH3)(py)}2(μ-L1)2] – Powder versus Single Crystal Study.

Caspar J. Schneider, John D. Cashion, Nicholas F. Chilton, Celine Etrillard, Mauricio Fuentealba, Judith A. K. Howard, Jean-Francois Létard, Carsten Milsmann, Boujemaa Moubaraki, Hazel A. Sparkes, Stuart R. Batten, Keith S. Murray, Eur. J. Inorg. Chem. 2013, 850.

 

27.

Synthesis, Electronic Structure and Alkene Hydrosilylation Activity of Terpyridine and Bis(imino)pyridine Iron Dialkyl Complexes.

Aaron M. Tondreau, Crisita Carmen Hojilla  Atienza, Jonathan M. Darmon, Carsten Milsmann, Helen M. Hoyt, Keith J. Weller, Susan A. Nye, Kenrick M. Lewis, Julie Boyer, Johannes G. P. Delis, Emil Lobkovsky, Paul J. Chirik, Organometallics 2012, 31, 4886.

 

26.

Azo N=N Bond Cleavage with a Redox-Active Vanadium Compound Involving Metal-Ligand Cooperativity.

Milsmann, C., Turner, Z. R., Semproni, S. P., Chirik, P. J., Angew. Chem. Int. Ed. 2012, 51, 5386.

 

25.

Side-on Dinitrogen Complexes of Titanocenes with Disubstituted Cyclopentadienyl Ligands: Synthesis, Structure and Spectroscopic Characterization.

Semproni, S. P., Milsmann, C., Chirik, P. J., Organometallics 2012, 31, 3672.

 

24.

Structure and Reactivity of a Hafnocene µ-Nitride Prepared From Dinitrogen Cleavage.

Semproni, S. P., Milsmann, C., Chirik, P. J., Angew. Chem. Int. Ed. 2012, 51, 5213.

 

23.

Bis(imino)pyridine Iron Dinitrogen Compounds Revisited: Differences in Electronic Structure Between Four- and Five-Coordinate Derivatives.

Stieber, S. C. E., Milsmann, C., Hoyt, J. M., Turner, Z. R., Finkelstein, K. D., Wieghardt, K., DeBeer, S., Chirik, P. J., Inorg. Chem. 2012, 51, 3770.

 

22.

Synthesis and Electronic Structure Determination of N-Alkyl-Substituted Bis(imino)pyridine Iron Imides Exhibiting Spin Crossover Behavior.

Bowman, A. C., Milsmann, C., Bill, E., Turner, Z. R., Lobkovsky, E., DeBeer, S., Wieghardt, K., Chirik, P. J., J. Am. Chem. Soc. 2011, 133, 17353.

 

21.

Synthesis, Electronic Structure and Ethylene Polymerization Activity of Bis(imino)pyridine Cobalt Alkyl Cations.

Atienza, C. C. H., Milsmann, C., Lobkovsky, E., Chirik, P. J., Angew. Chem. Int. Ed. 2011, 50, 8143.

 

20.

Oxidation and Reduction of Bis(imino)pyridine Dicarbonyl Complexes.

Tondreau, A. M., Milsmann, C., Lobkovsky, E., Chirik, P. J., Inorg Chem. 2011, 50, 9888.

 

19.

Spin States and Redox Changes in Iron bis-terdentate Nitroxide {NNO} Chelates.

Murray, K., Gass, I., Gartshore, C., Lupton, D., Moubaraki, B., Nafady, A., Bond, A., Boas, J., Cashion, J., Milsmann, C., Wieghardt, K., Inorg. Chem. 2011, 50, 3052.

 

18.

Synthesis, Electronic Structure and Catalytic Activity of Reduced Bis(aldimino)pyridine Iron Compounds: Experimental Evidence for Ligand Participation.

Russell, S. K., Milsmann, C., Lobkovsky, E., Weyhermüller, T., Chirik, P. J., Inorg. Chem. 2011, 50, 3159.

 

17.

Synthesis and Electronic Structure of Cationic, Neutral and Anionic Bis(imino)pyridine Iron Alkyl Complexes: Evaluation of Redox Activity in Single Component Ethylene Polymerization Catalysts.

Tondreau, A. M., Milsmann, C., Patrick, A. D., Hoyt, H. M., Lobkovsky, E., Wieghardt, K., Chirik, P. J., J. Am. Chem. Soc. 2010, 132, 15046.

 

16.

Reduced N-Alkyl Substituted Bis(imino)pyridine Cobalt Complexes: Molecular and Electronic Structures for Compounds Varying by Three Oxidation States.

Bowman, A. C., Milsmann, C., Bill, E., Lobkovsky, E., Weyhermüller, T., Wieghardt, K., Chirik, P. J., Inorg. Chem. 2010, 49, 6110.

 

15.

Stabilization of High-Valent FeIVS6-Cores by Dithiocarbamate(1-) and 1,2-Dithiolate(2-) Ligands in Octahedral [FeIV(Et2dtc)3-n(mnt)n](n-1)- Complexes (n = 0, 1, 2, 3). A Spectroscopic and Density Functional Theory Computational Study.

Milsmann, C., Sproules, S., Bill, E., Weyhermüller, T., DeBeer George, S., Wieghardt, K., Chem. Eur. J. 2010, 16, 3628.

 

14.

Synthesis, Molecular and Electronic Structures of Reduced Bis(imino)pyridine Cobalt Dinitrogen Complexes: Ligand versus Metal Reduction.

Bowman, A. C., Milsmann, C., Hojilla Atienza, C. C., Lobkovsky, E., Wieghardt, K., Chirik, P. J., J. Am. Chem. Soc. 2010, 132, 1676.

 

13.

Reversible P4 Activation with Nickel(I) and a η3-Coordinated Tetraphosphorus Ligand between Two Ni(I) Centers.

Yao, S.,  Xiong, Y., Milsmann, C., Bill, E., Pfirrmann, S., Limberg, C., Driess, M., Chem. Eur. J. 2010, 16, 436.

 

12.

Electronic Structures of [RuII(cyclam)(Et2dtc)]+, [Ru(cyclam)(tdt)]+, and [Ru(cyclam)(tdt)]2+. An X-Ray Absorption Spectroscopic and Computational Study (tdt = toluene-3,4-dithiolate; Et2dtc = N,N-diethyldithiocarbamate(1-)).

Milsmann, C., Bill, E., Weyhermüller, T., DeBeer George, S., Wieghardt, K., Inorg. Chem. 2009, 48, 9754.

 

11.

Octahedral Monodithiolene Complexes of Iron: Characterization of S,S′-Coordinated Dithiolate(1-) π Radical Monoanions. A Spectroscopic and Density Functional Theoretical Investigation.

Milsmann, C., Patra, G. K., Bill, E., Weyhermüller, T., DeBeer George, S., Wieghardt, K., Inorg. Chem. 2009, 48, 7430.

 

10.

Octahedral Monodithiolene Complexes of Cobalt(III) and Chromium(III). Spectroscopic and Density Functional Theoretical Characterization of S,S´-Coordinated Benzene-1,2-dithiolate(1-) π Radicals.

Milsmann, C., Bothe, E., Bill, E., Weyhermüller, T., Wieghardt, K., Inorg. Chem. 2009, 48, 6211.

 

9.

Facile Dissociation of [(LNiII)2E2] Dichalcogenides (E = Se, Te): Evidence for [LNiIIE2] Superselenides and Supertellurides in Solution.

Yao, S., Xiong, Y., Zhang, X., Milsmann, C., Schwarz, H., Driess, M., Angew. Chem. 2009, 121, 4621.

 

8.

Reduction Chemistry of Aryl- and Alkyl-Substituted Bis(imino)pyridine Iron Dihalide Compounds: Molecular and Electronic Structures of [(PDI)2Fe].

Wile, B. M., Trovitch, R. J., Bart, S. C., Tondreau, A. M., Lobkovsky, E., Milsmann, C., Bill, E., Wieghardt, K., Chirik, P. J.,  Inorg. Chem. 2009, 48, 4190.

 

7.

The Striking Stabilization of Ni06-Arene) Complexes by an Ylide-Like Silylene Ligand.

Meltzer, A., Präsang, C., Milsmann, C., Driess, M., Angew. Chem. Int. Ed. 2009, 48, 3170.

 

6.

Bis-picket-fence corroles.

Bröring, M., Milsmann, C., Ruck, S., Köhler, S., J. Organomet. Chem. 2009, 694, 1011.

 

5.

Investigating different strategies towards the preparation of chiral and achiral bis-picket fence corroles.

Bröring, M., Funk, M., Milsmann, C., J. Porph. Phthalocyanines 2009, 13, 107.

 

4.

A "side-on" superoxonickel complex [LNi(O2)] with a square-planar tetracoordinate nickel(II) center and its conversion into [LNi(µ-OH)2NiL].

Yao, S., Bill, E., Milsmann, C., Wieghardt, K., Driess, M., Angew. Chem. Int. Ed. 2008, 47, 7110.

 

3.

From a Paramagnetic, Mononuclear Supersulfidonickel(II) Complex to a Diamagnetic Dimer with a Four-Sulfur Two-Electron Bond. Yao, S., Milsmann, C., Bill, E., Wieghardt, K., Driess, M., J. Am. Chem. Soc. 2008, 130, 13536.

 

2.

One- and Two-Electron Reduced 1,2-Diketone Ligands in [ZnII(L)2(Et2O)], [CoII(L)2(Et2O)], and Na2(Et2O)4[CoII(LRed)2].

Spikes, G. H., Milsmann, C., Bill, E., Weyhermüller T.,  Wieghardt, K., Inorg. Chem. 2008, 47, 11745.

 

1.

Charge Distribution in Chromium and Vanadium Catecholato Complexes: X-Ray Absorption Spectroscopic and Computational Study.

Milsmann, C., Levina, A. Harris, H. H., Foran, G. J., Turner, P., Lay, P. A., Inorg. Chem. 2006, 45, 4743.

 

© 2018, Milsmann Group