Welcome to The SHI Group

 

 

        Home

        Michael Shi

        Publication

        Research

        Courses

        Group Members

        Links

        Contact

 

 

 

 

 

 

 

 

 

 

Postdoc position Opening

 

 

Publication Lists:

 

Independence Research Publications from WVU:

 

2015

(72) Peng, H.; Akhmedov, N. G.; Liang, Y.; Jiao, N.*; Shi, X.* "Synergistic Gold and Iron Dual Catalysis: Preferred Radical Addition toward Vinyl-Gold Intermediate over Alkene" J. Am. Chem. Soc. 2015, Accepted. (PDF)

(71) Cai, R.; Lu, M.; Aguilera, E. Y.; Xi, Y.; Akhmedov, N. G.; Petersen, J. L.; Chen, H.*; Shi, X.* "Ligand-Assisted Gold-Catalyzed Cross-Coupling with Aryldiazonium Salts: A Case of External Oxidant Free Redox Gold Catalysis"Angew. Chem. Int. Ed. 2015, Accepted. (PDF)

(70) Ye, X.; Petersen, J. L.; Shi, X.* “Nickel-Catalyzed Directed Sulfenylation of sp2 and sp3 C-H Bonds" Chem. Commun. 2015, 51, 7863 - 7866. (PDF)

(69) Shi, Y.; Ye, X.; Gu, Q.;Shi, X.*; Song, Z.* “Facile Synthesis and Stereo-Resolution of Chiral 1,2,3-Triazole"Org. Biomol. Chem. 2015, 13, 5407-5411. (PDF)

(68) Dong, B.; Su, Y.; Ye, X.; Petersen, J. L.; Shi, X.* “Synthesis and Characterization of Fluorescent-Active Triazole-Gold Complexes" Sci. China Chem. 2015, 58, 1235-1238. (PDF)

(67) Zhang, Y.; Ye, X.; Petersen, J. L.; Li, M.*; Shi, X.* “Synthesis and Characterization of Bis-N-2-Aryl Triazole as Fluorophore" J. Org. Chem. 2015, 80,3664-3669. (PDF)

(66) Gao, W.; Ca, R.; Pham, T.; Forrest, K. A.; Hogan, A.; Nugen, P.; Williams, K.; Wojtas, L.; Luebke, R.; Weseliński, L. J.; Zaworotko, M. J.; Space, B.; Chen, Y.; Eddaoudi, M.;* Shi, X.;* Ma, S.* “Remote Stabilization of Copper Paddlewheel Based Molecular Building Blocks in Metal Organic Frameworks" Chem. Mater. 2015, 27, 2144-2151. (PDF)

(65) Su, Y.; Petersen, J. L.; Gregg, T. L.; Shi, X.* “Ambient Benzotriazole Ring Opening through Intermolecular Radical Addition to Vinyltriazole" Org. Lett. 2015, 17, 1208-1211. (PDF)

(64) Motika, S. E.; Wang, Q.; Ye, X.; Shi, X.* “Ambient Synthesis of Dienals via Triazole-Au and Amine Catalysis Relay" Org. Lett. 2015, 17, 290-293. (PDF)

(63) Cai, R.; Yan, W.; Bologna, M. G.; de Silva, K.; Finklea, H. O.; Petersen, J. L.; Shi, X.* “Synthesis and Characterization of N-2-Aryl-1,2,3-Triazole Based Iridium Complexes as Photocatalysts with Tuneable Photoredox Potential " Org. Chem. Front. 2015, 2, 141-144. (PDF)

2014

(62) Peng, H.; Xi, Y.; Ronaghi, N.; Dong, B.; Akhmedov, N. G.; Shi, X.* “Gold-Catalyzed Oxidative Cross-Coupling of Termina Alkynes: Selective Synthesis of Unsymmetrical 1,3-Diynes" J. Am. Chem. Soc. 2014, 136, 13174-13177. (PDF)

(61) Ye, X.; Shi, X.* “Palladium Catalyzed Aerobic Oxidative C-H Olefination with Removable 1, 2, 3-Triazole Directing Group" Org. Lett. 2014, 16, 4448-4451. (PDF)

(60) Xi, Y.; Su, Y.; Yu, Z.; Dong, B.; McClain, E. J.; Lan, Y.*; Shi, X.* “Chemoselective Carbophilic Addition of α-Diazoesters through Ligand-Controlled Gold Catalysis ” Angew. Chem. Int. Ed. 2014, 53, 9817-9821. (PDF)

(59) Senty, T. R.; Yalamanchi, M.; Zhang, Y.; Cushing, S. K.; Seehra, M. S.; Shi, X.; Bristow, A. D.* “Photoluminescence spectroscopy of YVO4:Eu3+ nanoparticles with aromatic linker molecules: a precursor to biomedical functionalization” J. Appl. Phys. 2014,115, 163107. (PDF)

(58) Feng, P.; Sun, X.; Su, Y.; Li, X.; Zhang, L.; Shi, X.*; Jiao, N.* “Ceric Ammonium Nitrate (CAN) Catalyzed Modification of Ketones via Two C-C Bond Cleavages with the Retention of the Oxo-Group” Org. Lett. 2014, 16, 3388-3391. (PDF)

(57) Gautam, L. N.; Su, Y.; R.; Akhmedov, N. G.; Petersen, J. L.; Shi, X.* “Asymmetric synthesis of substituted NH-piperidines from chiral amines”Org. Biomol. Chem. 2014, 12, 6384-6388. (PDF)

(56) Cai, R.; Wang, D.; Chen, Y.; Yan, W.; Geise, N. R.; Sharma, S.; Li, H.; Petersen, J. L.;Li, M.*; Shi, X.* “Facile synthesis of fluorescent active triazapentalenes through gold-catalyzed triazole–alkyne cyclization” Chem. Commun. 2014, 50, 7303-7305. (PDF)

(55) Su, Y.; Zhang, Y.; Akhmedov, N. G.; Petersen, J. L.; Shi, X.* “Ambient Intermolecular [2 + 2] Cycloaddition: An Example of Carbophilicity and Oxophilicity Competition in Au/Ag Catalysis” Org. Lett. 2014, 16, 2478-2481. (PDF)

(54) Wang, Q.; Motika, S. E.; Akhmedov, N. G.; Petersen, J. L.; Shi, X.* “Synthesis of Cyclic Amine Borane Through Triazole-Gold(I) Catalyzed Alkyne Hydroboration” Angew. Chem. Int. Ed. 2014, 53, 5418-5422. (PDF)

(53) Xi, Y.; Dong, B.; McClain, E. J.; Wang, Q.; Gregg, T. L.; Akhmedov, N. G.; Petersen, J. L.; Shi, X.* "Gold-Catalyzed Intermolecular C-S Bond Formation: Efficient Synthesis of a-Substituted Vinyl Sulfones" Angew. Chem. Int. Ed. 2014, 53, 4657-4661. (PDF)

(52) Xi, Y.; Wang, Q.; Su, Y.; Li, M.*; Shi, X.* "Quantitative Kinetic Investigation of Triazole-Gold(I) Complex Catalyzed [3,3]-Rearrangement of Propargyl Ester" Chem. Commun. 2014, 50, 2158-2160. (PDF)

(51) Su, Y.; Lu, M.; Dong, B.; Chen, H.*; Shi, X.* "Silver Catalyzed Alkyne Activation: the Surprising Ligand Effect" Adv. Syn. Cat . 2014, 356, 692-696.(PDF)

(50) Xi, Y.; Wang, D.; Ye, X.; Akhmedov, N. G.; Petersen, J. L.; Shi, X.* "Synergistic Au/Ga Catalysis in Ambient Nakamura Reaction" Org. Lett. 2014, 16, 306-309. (PDF)

 

2013

(49) Chen, Y.*; Zhou, S.; Ma, S.; Liu, W.; Pan, Z.; Shi, X.* "A facile synthesis of 5-amino-[1,2,3]triazolo[5,1-a]isoquinoline derivatives through copper-catalyzed cascade reactions" Org. Biomol. Chem. 2013, 11, 8171-8174. (PDF)

(48) Gao, W.; Cai, R.; Meng, L.; Wojtas, L.; Zhou, W.; Yildirim, T.; Shi, X.*; Ma, S.* "Quest for a highly connected robust porous metal–organic framework on the basis of a bifunctional linear linker and a rare heptanuclear zinc cluster" Chem. Commun. 2013, 49, 10516-10518.(PDF)

(47) Xi, Y.; Dong, B.; Shi, X.* "Ambient gold-catalyzed O-vinylation of cyclic 1,3-diketone: A vinyl ether synthesis" Beilstein J. Org. Chem. 2013, 9, 2537–2543. (PDF)

(46) Xi, Y.; Shi, X.* "Cinchonine and thiourea" Chem. Commun. 2013, 49, 8583-8585. (PDF)

(45) Ye, X.; He, Z.; Ahmed, T.; Weise, K.; Akhmedov, N. G.; Petersen, J. L.; Shi, X.* "1,2,3-Triazoles as versatile directing group for selective sp2 and sp3 C–H activation: cyclization vs substitution" Chem. Sci. 2013, 4, 3712-3716. (PDF)

(44) Yan, W.; Shi, X.*; Zhong, C.* "Secondary Amines as Lewis Bases in Nitroalkene Activation" Asian J. Org. Chem. 2013, 2, 904-914. (PDF)

(43) Wang, K.; Chen, M.; Wang, Q.; Shi, X.*; Lee, J. K.* "1,2,3-Triazoles: Gas Phase Properties"J. Org. Chem. 2013, 78, 7249-7258. (PDF)

(42) Ma, Z.; Sun, W.; Chen, L,; Li, J.; Liu, Z.; Bai, H.; Zhu, M.; Du, L.; Shi, X.; Li, M.* "A novel hydrazino-substituted naphthalimide-based fluorogenic probe for tert-butoxy radicals"Chem. Commun. 2013, 49, 6295-6297. (PDF)

(41) Gautam, L. N.; Wang, Q.; Akhmedov, N. G.; Petersen, J. L.; Shi, X.* "Stereoselective synthesis of N-heterocycles through amine addition to nitroalkenes" Org. Biomol. Chem. 2013, 12, 1917-1920. (PDF)

(40) Wang, L.; Zhang, J.; Sun, J.; Zhu, L.; Zhang, H.; Liu, F.; Zheng, D.; Meng, X.; Shi, X.*; Xiao, F.* "Copper-Incorporated Porous Polydivinylbenzene as Efficient and Recyclable Heterogeneous Catalyst in Ullmann Biaryl Ether Coupling" ChemCatChem, 2013, 5, 1606-1613. (PDF)

(39) Wang, C.; Wang, Y.; Xu, L.; Shi, X.; Li, X.; Xu, X.; Sun, H.; Yang, B.; Lin, Q.* "A Galvanic Replacement Route to Prepare Strongly Fluorescent and Highly Stable Gold Nanodots for Cellular Imaging" Small, 2013, 9, 413-420. (PDF)

 

2012

(38) Gao, W.; Yan, W.; Cai, R.; Williams, K.; Salas A.; Wojtas, L.; Shi, X.*; Ma, S.* "A pillared metal-organic framework incorporated with 1,2,3-triazole moieties exhibiting remarkable enhancement of CO2 uptake" Chem. Commun. 2012, 48, 8898-8900. (PDF)

(37) Wang, D.; Cai, R.; Sharma, S.; Jirak, J.; Thummanapelli, S. K.; Akhmedov, N. G.; Zhang, H.;Liu, X.; Petersen, J. L.; Shi, X.* "'Silver Effect' in Gold(I) Catalysis: An Overlooked Important Factor" J. Am. Chem. Soc. 2012, 134, 9012-9019. (PDF)

(36) He, W.; Zhang, F.; Shi, X.*; Li, H.* "Ordered Mesoporous Proline Organocatalyst with High Activity and Strong Durability in Promoting Intermolecular Cross-Conjugated Additions" Eur. J. Org. Chem. 2012, 20, 3753-3758. (PDF)

(35) Yan, W.; Ye, X.; Akhmedov, N. G.; Petersen, J. L.; Shi, X.* "1,2,3-Triazole: Unique Ligand in Promoting Iron-Catalyzed Propargyl Alcohol Dehydration" Org. Lett. 2012, 14, 2358-2361. (PDF)

(34) Wang, C.; Xu, L.; Wang, Y.; Zhang, D.; Shi, X.*; Dong, F.; Yu, K.; Lin, Q.*; Yang, B. "Fluorescent Silver Nanoclusters as Effective Probes for Highly Selective Detection of Mercury(II) at Parts-per-Billion Levels" Chem. Asian. J. 2012, 7, 1652-1656. (PDF)

(33) Gao, W.; Yan, W;,Cai, R.; Meng, L.; Salas, A.; Wang, X.; Wojtas, L.; Shi, X.*; Ma, S.* "Porous Double-Walled Metal Triazolate Framework Based upon a Bifunctional Ligand and a Pentanuclear Zinc Cluster Exhibiting Selective CO2 Uptake" Inorg. Chem. 2012, 51, 4423-4425. (PDF)

(32) Yan, W.; Ye, X.; Weise, K.; Petersen, J. L.; Shi, X.* "Synthesis of allene triazole through iron catalyzed regioselective addition to propargyl alcohols" Chem. Commun. 2012, 48, 3521-3523.(PDF)

(31) Wang, Q.; Aparaj, S.; Akhmedov, N. G.; Petersen, J. L.; Shi, X.* "Ambient Schmittel Cyclization Promoted by Chemoselective Triazole-Gold Catalyst" Org. Lett. 2012, 14, 1334-1337.(PDF)

 

2011

(30) Wang, D.; Zhang, Y.; Harris, A.; Gautam, L. N. S.; Shi, X.* "Triazole-Gold Promoted Effective Synthesis of Enone from Propargyl-Esters and Alcohols: a Catalyst Offered Chemo-Selectivity, Acidity and Ligand Economy" Adv. Syn. Cat. 2011, 353, 2584-2588. (Abstract) (PDF

(29) Yan, W.; Liao, T.; Tuguldur, O.; Zhong, C.; Petersen, J. L.; Shi, X.* "Mitsunobu Reaction of the 1,2,3-NH-Triazoles: A regio- and stereo-selective approach in reaching functional triazole derivatives"  Chem. Asian. J. 2011, 6, 2720-2724.  (Abstract) (PDF

(28) Li, M.; Wang, Q.; Shi, X.; Hornak, L. A.; Wu, N.* "Detection of Mercury(II) by Quantum Dot/DNA/Gold Nanoparticle Ensemble Based Nanosensor Via Nanometal Surface Energy Transfer"  Anal. Chem. 2011,83, 7061-7065.  (PDF) 

(27) Wang, D.; Zhang, Y.; Cai, R.; Shi, X.* "Triazole-Au(I) Complex as Chemoselective Catalyst in Promoting Propargyl Ester Rearrangements"  Beilstein J. Org. Chem. 2011, 7, 1014–1020. [special issue on gold catalysis]  (Abstract) (PDF) 

(26) Li, M.; Cushing, S. K.; Wang, Q.; Shi, X.; Hornak, L. A.; Hong, Z.; Wu, N.* "Size-Dependent Energy Transfer between CdSe/ZnS Quantum Dots and Gold Nanoparticles"  J. Phys. Chem. Lett. 2011, 2,  2125-2129.  (PDF) 

(25) Wang, D.; Gautam, L. N. S.; Bollinger, C.; Harris, A.; Li, M.; Shi, X.* "1,2,3-Triazole Bound Au(I) (TA-Au) as Chemoselective Catalysts in Promoting Asymmetric Synthesis of Substituted Allenes"  Org. Lett. 2011, 13, 2618-2621. (Abstract) (PDF) 

(24) Yan, W.; Wang, Q.; Lin, Q.; Li, M.; Petersen, J. L.; Shi, X.* "N-2-Aryl-1,2,3-Triazoles: A New Class of UV-Blue Emitting Fluorophores with Tunable Optical Properties" Chem. Eur. J. 2011, 17, 5011-5018. (Abstract) (PDF)

(23) Zhong, C.; Gautam, L. N. S.; Wang, D.; Akhmedov, N.; Petersen, J. L.; Shi, X.* "Amine Nucleophilic Addition to Nitroalkene as a New Practical Approach for the Synthesis of Fully Substituted Isoxazoline-N-Oxide" Tetrahedron 2011 67, 4402-4411.  
I
 (Abstract) (PDF

2010

(22) Yan, W.; Wang, Q.; Chen, Y.; Petersen, J. L.; Shi, X.* "Iron Catalyzed C-O Bond Activation for the Synthesis of Propargyl-1,2,3-Triazoles and 1,1-Bis-Triazoles" Org. Lett. 2010, 12, 3308-3311.  (Abstract) (PDF

(21) Chen, Y.; Wang, D.; Petersen, J. L.; Akhmedov, N.Shi, X.* "Synthesis and Characterization of Organogold Complexes Containing Acid Stable Au-C bond through Triazole-yne 5-Endo-Dig Cyclization"  Chem. Commun. 2010, 46, 6147 - 6149. (Abstract) (PDF

(20) Zhong, C.; Gautam, L. N. S.; Petersen, J. L.; Akhmedov, N.Shi, X.* "Concise Asymmetric Synthesis of Fully Substituted Isoxazoline-N-Oxide through Lewis Base Catalyzed Nitroalkene Activation Chem. Eur. J. 2010, 16, 8605-8609.  (Abstract) (PDF) 

(19) Sengupta, S.; Shi, X.* "Recent Advances in Asymmetric Gold Catalysis ChemCatChem 2010, 2, 609-619.  (PDF)


(18) Zhong, C.; Shi, X.* "When Organocatalysis Meets Transition Metal Catalysis Eur. J. Org. Chem. 2010, 2999-3025.  (PDF)

(17) Wang, D.; Ye, X.; Shi, X.* "Efficient Synthesis of E-a-Haloenones Through Chemoselective Alkyne Activation Over Allene with Triazole-Au Catalysts Org. Lett. 2010, 12, 2088-2091.  (Abstract) (PDF)

(16) Zhong, C.; Liao, T.; Tuguldur, O.; Shi, X.* "One-Pot Synthesis of Substituted Di-Hydrofurans from Lewis Base-Catalyzed Three-Component Condensation Org. Lett. 2010, 12, 2064-2067.  (Abstract) (PDF)

(15) Chen, Y.; Yan, W.; Akhmedov, N.; Shi, X.* "1,2,3-Triazole as Special “X-Factor” in Promoting Hashmi Phenol Synthesis Org. Lett. 2010, 12, 344-347.  (Abstract)  (PDF)

2009

(14) Liao, W.; Chen, Y.; Duan, H.; Liu, Y.; Petersen, J. L.; Shi, X.* " 1,2,3-Triazole-boranes: stable and efficient reagents for ketone and aldehyde reductive amination in organic solvents or in water" Chem. Commun. 2009, 6436-6438.  (Abstract)  (PDF)

(13) Chen, Y.; Zhong, C.; Sun, X.; Akhmedov, N.; Petersen, J. L.; Shi, X.* " One-pot cascade Michael–Michael–Aldol condensation for diastereoselective synthesis of nitro-substituted cyclohexanes" Chem. Commun. 2009, 5150-5152.  (Abstract)  (PDF).

(12) Duan, H.; Sengupta, S.; Petersen, J. L.; Akhmedov, N.; Shi, X.* " Triazole-Au(I) Complexes: A New Class of Catalysts with Improved Thermal Stability and Reactivity for Intermolecular Alkyne Hydroamination" J. Am. Chem. Soc. 2009, 131, 12100-12102.  (Abstract)  (PDF).

(11) Chen, Y.; Zhong, C.; Petersen, J. L.; Akhmedov, N.; Shi, X.* " One-Pot Asymmetric Synthesis of Substituted Piperidines by Exocyclic Chirality Induction" Org. Lett. 2009, 11, 2333-2336. (Abstract) (PDF)

(10) Duan, H.; Yan, W.; Sengupta, S.;  Shi, X.* "Highly efficient synthesis of vinyl substituted triazoles by Au(I) catalyzed alkyne activation " Bioorg. Med. Chem. Lett.  2009,3899-3902.   (Abstract)  (PDF).

(9) Duan, H.; Sengupta, S.; Petersen, J. L.; Shi, X.* "Synthesis and Characterization of NH-triazole-Bound Rhodium(I) Complexes: Substituted-Group-Controlled Regioselective Coordination" Organomatellic  2009, 2352-2355.  (Abstract)  (PDF)

(8) Zhong, C.; Chen, Y.; Petersen, J. L.; Akhmedov, N.; Shi, X.* "Enantioselective Intermolecular Crossed-Conjugate Additions between Nitroalkenes and a,b-Enals through a Dual Activation Strategy" Angew. Chem. Int. Ed.  2009, 48, 1279-1282. (Abstract)  (PDF)

2008

(7) Liu, Y.; Yan, W.; Chen, Y.; Petersen, J. L.; Shi, X.* "Efficient Synthesis of N-2-Aryl-1,2,3-Triazole Fluorophores via Post-Triazole Arylation" Org. Lett. 2008, 10, 5389-5392.(Abstract) (PDF)

(6) Duan, H.; Sun, X.; Liao, W.;  Petersen, J. L.; Shi, X.* "Proline as Lewis Base Catalyst: Diastereoselective Synthesis of Isoxazoline-N-oxide through [3 + 2] Cycloaddition" Org. Lett. 2008, 10, 4113-4116. (Abstract) (PDF)

(5) Chen, Y.; Liu, Y.; Petersen, J. L.; Shi, X.* "Conformational control in the regioselective synthesis of N-2-substituted-1,2,3-triazoles" Chem. Commun. 2008, 3254-3256. (Abstract) (PDF)

(4) Sengupta, S.; Duan, H.; Lu, W.; Petersen, J. L.; Shi, X.* "One Step Cascade Synthesis of 4,5-Disubstituted-1,2,3-(NH)-Triazoles" Org. Lett. 2008, 10, 1493-1494. (Abstract) (PDF)

2007

(3)  Sun, X.; Sengupta, S.; Petersen, J. L.; Wang, H.; Lewis, J. P.; Shi, X.* "Intermolecular Cross-Double-Michael Addition between Nitro and Carbonyl Activated Olefins as a New Approach in C-C Bond Formation" Org. Lett. 2007, 9, 4495-4498. (Abstract)  (PDF)

(2)   Zhong, C.; Wang, J.; Wu, N.; Wu, G.; Zavalij, P.; Shi, X.* "Anion bridged nanosheet from self-assembled G-quadruplexes" Chem. Commun. 2007, 3148-3150. (Abstract) (PDF)

(1)   Lu, W.; Senguputa, S.; Petersen, J.; Akhmedov, N.; Shi, X.* "Mitsunobu Coupling of Nucleobases and Alcohols: An Efficient, Practical Synthesis for Novel Nonsugar Carbon Nucleosides" J. Org. Chem. 2007, 72, 5012-5017. (Abstract) (PDF)

 


 

Last Update

12/08/2010